Q.

Select the correct statements about the compound NO+BF4-?

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a

B-F bond length in this compound is lower than that of BF3

b

Nitrogen-oxygen bond length in this compound is higher than that of nitric oxide (NO)

c

It is made of diamagnetic species

d

It has 5σ and 2π bonds

answer is A, B, C.

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Detailed Solution

NO+BF4-
Bond order of NO+ is 3, one sigma bond and two pi bond. Number of pi-bonds is 2 and sigma bond is 5.

Bond order of NO+ is 3.0 and NO is 2.5. Bond order is inversely proportional to bond length. 
NO+ is diamagnetic and BF4- is diamagnetic.

B−F bonds are longer in BF4- than in BF3 due to absence of pπ−pπ back bonding in BF4-.

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