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Q.

Select the correct statement(s) for following equilibrium:

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a

On increasing pressure, melting point decreases while boiling point increases for H2O

b

On increasing pressure, sublimation temperature · creases for both CO2 and H2O

c

On increasing pressure, sublimation temperature increases for CO2 but decreases for H2O

d

On increasing pressure, melting point and boiling point of CO2 increases

answer is A, B, C.

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Detailed Solution

(a) Phase diagram of CO2

Question Image

Line XY represents SL

As. P increases, on y-axis. M ·P increases on XY line

(b) Phase diagram of H2O

Question Image

As, pressure increases the value of melting point decreases and value of boiling point increases.

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