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Q.

Select the correct statements for the equilibrium under standard conditions
$H_{2} O (s) ⇌ H_{2} O (l) Δ {S^{0}}_{1}$
$H_{2} O (l) ⇌ H_{2} O (V a p) Δ {S^{0}}_{2}$
$Δ H_{2} O (s) ⇌ H_{2} O (V a p) Δ {S^{0}}_{3}$

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a

$Δ {S^{0}}_{1} > Δ {S^{0}}_{2}$

b

$Δ {S^{0}}_{2} > > > Δ {S^{0}}_{1}$

c

$Δ {S^{0}}_{3} > Δ {S^{0}}_{2}$

d

$Δ {S^{0}}_{3} > Δ {S^{0}}_{1}$

answer is B, C, D.

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Detailed Solution

$H_{2} O (S)$ more ordered arrangement.
$Δ {S^{0}}_{2} = {S^{0}}_{H_{2} O (V a p)} - {S^{0}}_{H_{2} O (l)}$
$Δ {S^{0}}_{1} = {S^{0}}_{H_{2} O (l)} - {S^{0}}_{H_{2} O (S)}$
Hence ${S^{0}}_{H_{2} O (V)}$ is maximum
$Δ {S_{2}}^{0} > > > Δ {S_{1}}^{0}$

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