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Q.

Select. the correct statements) from the following:

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a

Rate of sulphonation of C6H6 and C6D6 will be equal.

b

On treatment of salicylic acid with Br2/ water (in excess) it. result in a dibromo producL

c

Pyridine is less reactive than benzene toward: aromatic electrophiltc substitution.

d

Chlorobenzene gives m-dichloro benzene with Cl2FeCl3.

answer is C.

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Detailed Solution

Isotopic effect is observed in sulphonation. Salicylic acid gives 2,4,6-tribromophenol (i.e., decarboxv bromination takes place).

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