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Q.

Select the correct statement(s) regarding BrF5 molecule.

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a

All FBrFas square pyramidal shape

b

All bond angles are equal to 90°

c

All Br-F bond lengths are equal

d

All of the above

answer is A.

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Detailed Solution

Nodal plane is the molecular plane.BrF5 has a square bipyramidal structure and only one electron pair. a square pyramidal structure is created in this way. Axial lone pair and equatorial F's bond angle becomes deformed and is less than 90 degrees as a result of lone pair-bond pair repulsion.
As a result, none of the FBrF bond angles is 90°.

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