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Q.

Select the incorrect option for van der waals gas.

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a

He has smaller 'a' (van der Waals' constant than.NeKrArCO2 CH4 and NH3

b

He has smaller 'b' (van der Waals· constant than NeKrArCO2 CH4 and .NH3

c

At 273 K and 1, He molecules have attractions with respect to ideal behavior

d

At 273 K and 1, He molecules have repulsions with respect to ideal behaviour

answer is C.

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Detailed Solution

Due to weak intermolecular forces of attraction, he deviates from ideal behaviour (Z=1) i.e, Z>1 ,and as a result, an is very small P+an2V2(Vnb)=RT. Since an is so little, we can reject. aV2 (P)(Vnb)=RT(Z)

In He, repulsions dominate.

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