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Q.

Select the incorrect statement(s) about N2F4 and N2H4.

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a

The N-N bond energy in N2F4 is more than N-N bond energy in N2H4,

b

In N2F4, d-orbitals are contracted by electronegative fluorine atoms, but d-orbital contraction is not possible by H-atom in N2H4.
 

c

The N-N bond length in N2F2 is more than that of in N2H4.

d

The N-N bond length in N2F2 is less than that of in N2H4.

answer is A, C.

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Detailed Solution

In N2F2​, N—N bond has higher s-character. So, bond length decreases. 

In N2H4​, N—N bond has low s-character, so bond lengths increases. Thus, the order of bond length,

N2F2<N2H4

Hence, A and C are correct answer.

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