Select the option which is correct regarding true/false of the given statements :
Statement-1: Thermal decomposition of solid ${\mathrm{CaCO}}_3$ is expected to be spontaneous as high temperatures and non-spontaneous at low temperatures.
Statement-2: If the rate law for an acid catalysed reaction is $\mathrm{r} = \mathrm{K} {\left[\mathrm{Reactant}\right] }^1$$\left[\mathrm{Catalyst}\right] {°}^{ }$ then rate will be independent of presence / absence of catalyst.

Statement-3: When water freezes in a glass beaker, volume of the system increases at constant temperature and hence entropy will also increase.