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Q.

Select the total number of properties which are correct with respect to K4Fe(CN)5O2 or any of its isomors (d6 configuration of central metal ion).

(a) Paramagnetic 

(b) Inner orbital complex

(c) Low spin complex

(d) Δ0>P

(e) Shows optical isomerism 

(g) Shows linkage isomerism

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answer is 7.

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Detailed Solution

The oxidation number of given complex is,

K4+4FeCN551O2i

Here, the complex is paramagnetic with inner orbital and low spin. This shows optical, geometrical and linkage isomerism.

Hence, correct answer is 0007

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Select the total number of properties which are correct with respect to K4Fe(CN)5O2 or any of its isomors (d6 configuration of central metal ion).(a) Paramagnetic (b) Inner orbital complex(c) Low spin complex(d) Δ0>P(e) Shows optical isomerism (g) Shows linkage isomerism