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Q.

SEP for Sn4+/Sn+2 couple is +0.15V and that for Cr3+/Cr couple  is -0.74V. These two couples in their standard state are connected to make a cell. The cell potential will be

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a

+1.19V      

b

+0.18V

c

+0.89V

d

+1.83V      

answer is C.

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Detailed Solution

Ecell0=Ecathode0  Eanode0=0.150.74=+0.89V

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SEP for Sn4+/Sn+2 couple is +0.15V and that for Cr3+/Cr couple  is -0.74V. These two couples in their standard state are connected to make a cell. The cell potential will be