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Q.

Silicon is unable to form π – bond by lateral overlap which is reflected by which option of the following.

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a

SiO2 is a hard and high melting solid while CO2 is a gas

b

There is no allotrope of silicon equivalent to the graphite

c

N(SiH3)3 and N(CH3)3 are pyramidal.

d

Me2CCl2 upon hydrolysis yields Me2CO while Me2SiCl2 yields silicones

answer is B, C, D.

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Detailed Solution

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N(CH3)3 is pyramidal but N(SiH3)3 is planar

SiO2 is a hard and high melting solid as it exists as giant covalent polymer. 

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Silicon is unable to form π – bond by lateral overlap which is reflected by which option of the following.