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Q.

Silver can be separated from lead by ____?

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a

fractional crystallisation

b

amalgamation

c

cupellation

d

addition of Zn 

answer is D.

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Detailed Solution

Focus on the keyword ‘separated’. This is concentration.

The concentration of argentiferous lead is carried out by addition of Zn as Ag forms volatile alloy with Zn, which can be heated to separate Zn and Ag. This Ag is further purified by cupellation. Thus, cupellation is a verification technique not concentration. This entire process is called Parke's method.

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