Q.

Silver metal in ore is dissolved by potassium cyanide solution in the presence of air by the reaction

4 Ag+8 KCN+02+2H20 -4K[Ag(CN)+]4K0H

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a

The amount of oxygen used in this process is 0.742 g  (for 100 gm pure Ag).

b

The amount of KCN required to dissolve 100 g of pure Ag is 120 g.

c

The volume of oxygen used at STP is 5.25 liters.

d

The amount of oxygen used in this process is 7.40 g  (for 100 gm pure Ag).

answer is A, C, D.

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Detailed Solution

Number of moles of Agin 100 gm sample =100108=0.925

4 moles of Agreacts with 8 moles of KCN, hence  0.925 moles of Ag will react with 8×9254×65=120.25l of KcN

4 moles of Ag reacts with 1 mole of oxygen, thus 0.925 moles will react with 1×9254×32=7.40g

Oxygen volume used in the same procedure =1×0.9254×22.4=5.18 L5.20 L

Hence, options A, C and D are correct.

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