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Q.

Simplified absorption spectra of three complexes  (i),(ii)  and (iii)  of  M+n  ion are provided below , their  λmax     Values  are correct match between the complexes and their λmax   values is 

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i)  [M(CN)6 ](-6+n)     ii)  [MCl6]6+n    iii)  [M(NO2)6]-6+n

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a

Ai,    Biii,   Cii

b

Aiii,     Bi,      Cii

c

Aii  ,Bi,   Ciii

d

Ai      Bii         Ciii

answer is A.

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Detailed Solution

Ligan field strength  :  CN()>NO2>Cl 
As ligand field strength increases, the energy gap between  t2g   And eg increases.
So  λmax order [M(CN)6](-6+n))<[MCl6](-6+n)<[M(NO2 )6 ](-6+n)
 

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Simplified absorption spectra of three complexes  (i),(ii)  and (iii)  of  M+n  ion are provided below , their  λmax     Values  are correct match between the complexes and their λmax   values is i)  [M(CN)6 ](-6+n)     ii)  [MCl6]−6+n    iii)  [M(NO2)6]-6+n