Smallest bond angle is in ____?

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${SO}_{2}$

$H_{2} S$

${NH}_{3}$

$H_{2} O$

answer is B.

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Detailed Solution

As the number of lone pairs increases ( when hybridisation is same ), bond angles decreases. If hybridisation and number of lone pairs are same, then as the size of the central atom increases, bond angle decreases. In hydrogen sulphide the bond angle is $97^{0}$ and water it is $104^{0}$

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