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Q.

S.No.Column-I (In fused state)S.No.Column-II (Conductivity in Ohm–1cm–1)
A)H+p)350
B)Na+q)50
C)Li+r)39
D)Cs+s)77

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a

A-s; B-p; C-q; D-s

b

A-q; B-p; C-s; D-s

c

A-s; B-s; C-p; D-q

d

A-p; B-q; C-r; D-s

answer is A.

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Detailed Solution

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Conductivity K = C × la ; K = conductivity
C=(1/R)=(1×a)/(ρ×l)H+=349.80;Na+=50.11Li+=38.66;Cs+=77.30

Down the group as size of ion increases,degree of hydration decreases and size of hydrated ion decreases. Ionic mobility increases. Though H+ is small in size, it exists in aqueous medium as H3O+.

H+ continuosly oscillates between neighbouring water molecules due to which it's ionic mobility is very high.

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