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So far total six bicarbonates have been collected in solid state. Which of the following is known in solution state only?

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NH₄HCO₃

LiHCO₃

KHCO₃

CsHCO₃

answer is B.

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Detailed Solution

${LiHCO}_{3}$ does not exist as solid state. The Hydration energy of Lithium bicarbonates higher than lattice energy and it is difficult to separate it in to solid state from its aqueous solution.

Remember: KHCO₃ is dimeric while NaHCO₃ is polymeric.

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