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Q.

Sodium carbonate can be manufactured by Solvay's process but potassium carbonate cannot be prepared because

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a

$K_{2} {CO}_{3}$ is more soluble

b

$K_{2} {CO}_{3}$ is less soluble

c

${KHCO}_{3}$ is more soluble than ${NaHCO}_{3}$

d

${KHCO}_{3}$ is less soluble than NaHCO₃

answer is C.

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Detailed Solution

NaHCO₃ formed in the solvay's process can be separated easily as ppt. because it is less soluble than KHCO₃.

$2 {NaHCO}_{3} \overset{∆}{\to} {Na}_{2} {CO}_{3} + H_{2} O$

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