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Q.

Sodium cyclopentadienide exists as  NaC5H5.(THF)x. To determine the value of x, an experiment is performed by dissolving a small amount of the sample in water and titrating the formed NaOH with standard HCl solution.
NaC5H5.(THF)x+H2O NaOH+C5H6+xTHF 
Molecular formula of THF is C4H8O .
The following result data was collected from such an experiment:

 

Trial 1

Trial 2

Weight of NaC5H5.(THF)x

0.52 g

0.41 g

Volume of 0.1 M HCl required to titrate NaOH

 

10 mL

 

7.88 mL

The value of x is_____.
[Atomic weights: H = 1, C = 12, Na = 23]

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answer is 6.

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Detailed Solution

NaC5H5.(THF)x+H2O NaOH+C5H6+xTHF

nNaC5H5.(THF)x=nNaOH0.5288+72x=10×0.11000x=6

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