Q.

Sodium extract is heated with concentrated HNO3 before testing for halogens because :

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a

S2 and CN if present are decomposed by cone. HNO3 and hence do not interfere in the test

b

Ag reacts faster with halides in acidic medium

c

Ag2S and AgCN are soluble in acidic medium

d

silver halides are totally insoluble in nitric acid

answer is A.

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Detailed Solution

Before testing for halogens, sodium extract is heated with concentrated  because, if S2 and CN ions are present, they are destroyed by the concentrated HNO3  and do not interfere with the test.

Hence, the correct option is A.

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Sodium extract is heated with concentrated HNO3 before testing for halogens because :