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Q.

Sodium forms Na+ and not Na2+ because:

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a

none of the above

b

first ionization potential is small and the difference in first and second ionization potentials is very large

c

sodium contains only one electron in outermost shell

d

radius of Na+ is much smaller than of Na+

answer is B.

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Detailed Solution

  • Sodium forms Na+ ion but it does not form Na2+ because of the low value of (IE)1​ and high value of (IE)2​
  • Sodium has one valence electron. Sodium forms Na+ ion by losing its valence electron and attains the stable electronic configuration of Ne with a completed octet. 
  • This requires less energy. The removal of the second electron will break this stable electronic configuration and requires high energy.
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