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Q.

Sodium stearate forms associated colloids

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a

Due to orientation of hydrocarbon chain to wards centre of the micelle and COO- groups towards water

b

Due to association of Na+ions

c

Due to dissociation of stearate ion

d

Due to orientation of COO-  groups towards center of the micelle and hydrocarbon chain towards water

answer is C.

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Detailed Solution

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  •  At low concentrations, soaps and detergents behave like real solutions, but when they reach the Critical Micelle Concentration (CMC), which is 10-4M to 10-3M, they start to form colloids (tail). 

Hydrophilic (polar) is the COO-part(head). 

When the concentration is low, C17H35COO-Na+ions are present on the surface, with the COO- groups remaining in the water and the C17H35 chains remaining at the surface. Micelles are formed as a result of association above CMC, where the polar part (or) the anion part COO- are drawn into the bulk where they aggregate to form spherical shape with the C17H35 part (non-polar) toward the centre of the sphere and COO- part remaining outward on the surface of the sphere.

The anionic component is hydrophilic, whereas the hydrophobic hydrocarbon chain dissolves the grease deposit. 

Hence the correct option is (C).

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