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Q.

Sodium sulphate is soluble in water where as barium sulphate is sparingly soluble because :

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a

The hydration energy of sodium sulphate is less than its lattice energy. 

b

The lattice energy has no role to play in solubility

c

The lattice energy of barium sulphate is more than its hydration energy

d

The hydration energy of sodium sulphate is more than its lattice energy 

answer is A, B.

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Detailed Solution

BaSO4is sparingly soluble in water because its hydration energy is lesser than the lattice energy  and thus ions are not separated from each other. On the contrary in Na2SO4the hydration energy is more than its lattice energy, These ions are separated from each other

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