Q.

Sodium sulphate is soluble in water whereas barium sulphate is sparingly soluble because

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a

The lattice energy has no role to play in solubility 

b

The lattice energy of barium sulphate is more than its hydration energy 

c

The hydration energy of sodium sulphate is more than its lattice energy

d

The hydration energy of sodium sulphate is less than its lattice energy

answer is A, B.

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Detailed Solution

BaSO4 is sparing;-:; soluble in water because its hydration energy is lesser than the lattice energy and thus ions are not separated from each other. On the contrary in Na2SO4, the hydration energy is more than its lattice energy. Thus ions are separated from each other and pass in solution state.

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