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Q.

Solid ammonium carbamate it taken in an empty closed container and allowed to attain equilibrium as,

NH2COONH4(s)2NH3(g)+CO2(g);Kp=500

Choose the incorrect statements :

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a

On increasing the volume of container, total pressure decreases at new equilibrium.

b

On increasing temperature, total pressure increases at new equilibrium

c

On addition of more solid at equilibrium total pressure increases at new equilibrium

d

Equilibrium total pressure is 15 atm

answer is B, C.

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Detailed Solution

Here,

2P02×P0=500P0=5

PToal =2×5+5=15

So, option , B and C are correct

 

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