Q.

Solid ammonium hydrogen sulphide decomposes according to the equation NH4HS(s)NH3(g)+H2S(g) at 25°c.  If the total pressure at equilibrium is 0.5 atm, the equilibrium constant Kp is

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a

0.0625 atm 2

b

0.25 atm2

c

1.25 atm2

d

0.5 atm 2

answer is D.

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Detailed Solution

The given reaction belongs to heterogeneous equilibrium, in which gaseous products are always formed in equal number of moles. So, partial pressures of gases  PNH3=0.25 atm and PH2S=0.25 atm 

Kp=PNH3PH2S

=0.0625 atm2 

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