Q.

Solid KCIO3 is taken in a container maintained at constant pressure of 1 atm. Upon heating, following equilibria is set :

2KClO3(s)2KCl(s)+3O2(g)

If ΔH=25 kcal/mol and  ΔS=50 cal/Kat what temperature  equilibrium will be established in the container?

( Ignore variation of ΔH and ΔS with temperature.)

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a

5000 K

b

500 K

c

298 K

d

Data insufficient

answer is B.

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Detailed Solution

At equilibrium Gibbs energy is zero.

ΔG=ΔKTΔS=OT=ΔHΔS

T=25×100050=500 K
 

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