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Q.

Solids expand on heating because       

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a

Kinetic energy of the atoms increases

b

Total energy of the atoms increases

c

The potential energy curve is asymmetric about the equilibrium distance between neighbouring atoms

d

Potential energy of the atoms increases

answer is D.

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Detailed Solution

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The expansion of solids can be well understood by potential energy curve for two adjacent atoms in a crystalline solid as a function of their internuclear separation (r).
Question Image

At ordinary temperature : Each molecule of the solid vibrate about its equilibrium position P1 between A and B (r0 is the equilibrium distance of it from some other molecule)
At high temperature : Amplitude of vibration increase (C \leftrightarrow D and E \leftrightarrowF). Due to asymmetry of the curve, the equilibrium positions (P2 and P3) of molecule displaced. Hence it's distance from other molecule increases (r2 > r1 > r0).
Thus, on raising the temperature, the average equilibrium distance between the molecules increases and the solid as a whole expands

 

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