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Q.

Solubility of B(OH)2 in water at 250C is 107 M. The Ksp of B(OH)2 is

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a

4×1021M3

b

9×1021M3

c

2×1021M3

d

6×1021M3

answer is D.

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Detailed Solution

B(OH)2(S)  B2+(aq)107+2OH(aq)2×107+x

Where x is [OH] from water.

H2O(l)  H+x+OHx+2×107

kw=[H+][OH]

1014=x(x+2×107)x=2×107±4×104+4×10142

=2×107±22×1072=(21)×107M

Ksp of B(OH)2=107(2×107+(21)107)2=107(2+1)21014=5.827×1021M3

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