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Q.

Solubility of BaF2 in a solution of Ba(NO3)2 will be represented by the concentration term

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a

[Ba+2]

b

[F-]

c

12F-

d

2[NO3-]

answer is C.

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Detailed Solution

BaF2(s)BaF2S(aq)Ba+2S+C(aq)+2F-(2Saq)

BaNO32S(s)Ba+2(aC+Sq)+2NO3-2C(aq)

Due to common ion effect ,the solubility of BaF2 is highly suppressed.

C>>>S   OR C + S ~ C

Ksp = (S + C) x (2S)2

[F-] = 2S

F-2=S

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