Q.

Solubility of NaCI, Na2SO4 and Na3PO4 in water in increasing order is

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a

NaCl<Na2SO4<Na3PO4

b

Na3PO4<Na2SO4<NaCl

c

NaCl<Na3PO4<Na2SO4

d

Na2SO4<NaCl<Na3PO4

answer is B.

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Detailed Solution

Larger the ionic character, larger the solubility in water. Smaller the cation, larger the anion, larger the charge larger the covalent nature and thus, smaller the solubility.
Cation is identical 
Charge polarizing power Cl<SO42<PO43
Covalent nature NaCl<Na2SO4<Na3PO4
Solubility Na3PO4<Na2SO4<NaCl

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Solubility of NaCI, Na2SO4 and Na3PO4 in water in increasing order is