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Q.

Solubility of the alkaline earth metal sulphates in water decrease in the sequence

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a

Ca>Sr>Ba>Mg

b

Sr>Ca>Mg>Ba

c

Ba>Mg>Sr>Ca

d

Mg>Ca>Sr>Ba

answer is D.

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Detailed Solution

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BeSO4, and MgSO4 are readily soluble in water; the solubility decreases from CaSO4 to BaSO4. The greater hydration enthalpies of Be2+ and Mg2+ ions overcome the lattice enthalpy factor and therefore their sulphates are soluble in water.

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