Q.

Solution of a weak acid and its anion (that is, its conjugate base) or of a base and its common cation are buffered. When we add a small amount of acid or base to any one of them, the pH  of solution changes very little, pH  of buffer solution can be computed as

for  acidic buffer :pH=pKa+log[Conjugate  base][Acid]
for  basic buffer :pOH=pKb+log[Conjugate  acid][Base]
It is generally accepted that a solution has useful buffer capacity ( pH change resisting power) provided that the value of [salt or conjugate base]/[acid] for acidic buffer lies within the range of 1 : 10 to 10 : 1. Buffer capacity is maximum when [conjugate base] = [acid]

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