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Q.

Some CO2 gas was kept in a sealed container at a pressure of 1 atm and at 273 K . This entire amount of CO2 gas was later passed through an aqueous solution of Ca(OH)2. The excess unreacted Ca(OH)2 was later neutralized with 0.1 M of 40 mL HCl . If the volume of the sealed container of CO2 was x , then x is____cm3 (nearest integer).
[Given : The entire amount of CO2 (g) reacted with exactly half the initial amount of Ca(OH)2 present in the aqueous solution.]

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answer is 45.

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Detailed Solution

Let moles of CO2=n moles of Ca(OH)2 total initially =2n
excess Ca(OH)2=n
gm equivalent of Ca(OH)2= gm equivalent of HCl
n×2=0.1×401000×1n=2×103 Volume of CO2=2×103×22400=44.8cm3

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