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Q.

Some hydrogen like atoms in ground state absorb 'n' photons having same energy and on de-excitation it emits exactly 'n' photons. Then the energy of absorbed photon may be

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a

91.8 eV

b

48.4 eV

c

40.8 eV

d

54.4 eV

answer is A, B.

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Detailed Solution

.Number of dark lines(in absorption) i.e excitation = number of bright lines(in emission), i.e de-excitation
It is possible only when the e - is excited to n=2 from ground state
Clearly,  ΔE=91.8eV and 40.8eV are possible
The energy of electron in the first and second orbit is  13.6eV and 3.4eV.
The energy difference is 13.6-3.4=10.2eV

40.810.2=4 an integer

91.810.2=9.an integer

n=121    10.2Z210.2Z2=91.8    Z=310.2Z2=40.8    Z=2

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