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Q.

Some statements about the given equilibrium system are given below:

Fe+3(aq,Yellow) + SCN-(aq, Colorless)[Fe(SCN)2]+2(aq, deep red)

Correct statement among these  is

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a

Intensity of red color increases on adding oxalic acid to equilibrium mixture

b

Numerical value of Kc increases on adding Hg+2 to equilibrium mixture

c

Intensity of yellow color increases on adding KSCN to equilibrium mixture

d

When Hg+2 is added to equilibrium mixture intensity of red color decreases due to formation of stable complex [Hg(SCN)4]-2.

answer is D.

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Detailed Solution

Intensity of red color decreases on adding oxalic acid to equilibrium mixture

Numerical value of Kc remains same on adding Hg+2 to equilibrium mixture

Intensity of yellow color decreases on adding KSCN to equilibrium mixture

When Hg+2 is added to equilibrium mixture intensity of red color decreases due to formation of stable complex [Hg(SCN)4]-2.

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