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Q.

Some statements are given. Among them the correct statements are
a) IP2 of sodium is greater than that of magnesium
b) IP2 of lithium is greater than IP1 of helium
c) IP2 of sodium is greater than IP1 of neon
d) IP1 of oxygen is greater than that of nitrogen

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a

All are correct

b

Only a, b and c are correct

c

Only a and b are correct

d

Only a and d are correct

answer is B.

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Detailed Solution

a) IP2 of Na>Mg....True
    Na+ has inert gas configuration
b) IP2 of lithium means removal of electron from stable Li+ lon.
    Li+....1s2
    He....1s2
    Both Li+ and He have 1s2 configuration, but effective nuclear charge of Li+>He
    therefore  IP2 of Li > IP1 of He
   Thus, IP2 of Li>IP1 of He.....True
C)IP2 of Sodium  means removal of electron from stable Na+ ion.
    Na+....1s2 2s2 2p6
    Ne ....1s22p63p6
    Both Na+ and Ne  have 1s2 2s2 2p6 configuration but effective nuclear charge of Na+ > Ne
    therefore IP2 of Na > IP1 of Ne
   Thus IP2 of Na >IP1 of Ne.....True
D) IP1 of oxygen > Nitrogen........false

     Nitrogen has stable half filled electronic configuration. so, IP1 of Nitrogen is greater        than that of Oxygen.
    Thus a,b.c are correct

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