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Q.

Some statements regarding the reaction:
 Question Image
are given below. Select the correct statement(s).

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a

 Q1 is a pure compound and optically inactive due to internal compensation

b

Q2 is a binary mixture and is optically inactive due to external compensation.

c

In the P to Q1 conversion step the  Br2 adds on  P in a syn manner and the intermediate formed is a cyclic brominium ion.

d

P is a trans-alkene

answer is A, D.

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Detailed Solution

Addition of Br2 on an alkene is a trans-addition.  Q1 is a binary mixture and is optically inactive due to external compensation. Note that the alkene P formed (MeCH=CHEt) is an unsymmetrical alkene and hence anti addition of Br2 upon it will not yield meso-product.

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