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Q.

sp-hybridization : closer to nucleus : : shorter and stronger bond length : ?

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a

greater electronegativity

b

None of the above

c

equal electronegativity

d

lesser electronegativity

answer is A.

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Detailed Solution

Hybridization influences the bond length and bond enthalpy(strength) in organic compounds. The sp-hybrid orbital contains more s-character and hence it is closer to its nucleus and forms shorter and stronger bond than sp3 -hybrid orbital. The change in hybridization affects the electronegativity of carbon. The greater the s-character of the hybrid orbitals, the greater is the electronegativity.

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