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Q.

Spin only magnetic moment of an octahedral complex of Fe2+ in the presence of a strong field ligand in BM is

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a

3.46

b

2.82

c

0

d

4.89

answer is C.

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Detailed Solution

 

In presence of strong firld ligand ,o>P for Fe2+=[Ar]3d6 

Question Image

 

 

 

 

 

 

 

Number of unpainred electrons = 0 

Magnetic moment = 0 

In NiCl 

Ni2+=[Ar] 3d8

Number of unpaired electrons = 2

After formation of oxidized product [Ni(CN)6]-2 , Ni4+ is formed

Ni4+=[Ar] 3d6

CN is strong field ligand. 

Number of unpaired electron = 0

The charge is 2-0=2 

 

 

 

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