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Q.

'Spin only' magnetic moment of Ni in [Ni(dmg)2] is the same as that found in 

 

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a

 Ni in NiCl2PPh32

b

Mn in MnO4

c

 Co in CoBr42

d

Pt in PtH2O2Br2

answer is B, D.

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Detailed Solution

Ni [Ni (dmg)2] complex is square planar and diamagnetic. Pt (II) have 5d8 configuration. The complex is square planar and therefore, diamagnetic. So,  μB.M=0.

This is same as the Mn in MnO4 and Pt in PtH2O2Br2.

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