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Q.

Stabilisation energy of octahedral complex with d7 configuration 
A) 1.8 Δ0  with one unpaired electron 
B) 1.8 Δ0  with three unpaired electrons
C) 0.8 Δ0  with one unpaired electron
D) 0.8  Δ0 with three unpaired electrons

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a

A and D

b

A and B

c

C and D

d

B and C

answer is A.

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Detailed Solution

For strong field ligands -CFSE=6×0.41×0.6=1.8Δ0
one unpaired electron
For weak field ligands 
CFSE=5×0.42×0.6=0.8Δ0 three unpaired electrons

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Stabilisation energy of octahedral complex with d7 configuration A) 1.8 Δ0  with one unpaired electron B) 1.8 Δ0  with three unpaired electronsC) 0.8 Δ0  with one unpaired electronD) 0.8  Δ0 with three unpaired electrons