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Q.

Stability constant is more for the complex:

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a

AgNH32+

b

CuNH342+

c

AgCN21

d

CoNH363+

answer is D.

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Detailed Solution

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Complex will be more stable if higher value of charge density is present.

Charge density = ChargeRadius

For stability:
(i) More basic ligand, then complex will be more stable.
(ii) Higher the oxidation state of central atom and higher is its coordination number.
(iii) Higher the stability constant (K)

 CoNH363+CuNH342+Stabilityconstant K5×10334×1011 AgNH32+AgCN21Stabilityconstant (K)1.6×1071×1022

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