Q.

Stabitlity of carbocation depends various electronic effects. Least stable carbocation among the following is

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a

H3CC+H2

b

O2NC+H2

c

H3COC+H2

d

OHCC+H2

answer is A.

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Detailed Solution

1)Electron withdrawing power of  NO2>CHO      

EWG  the stability of carbocation by intensifying the positive charge

2)Electron donating power of  OCH3>CH3

 EDG  the stability of carbocation by dispersing the positive charge
  Stability of 1 < 2 < 4 < 3

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