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Q.

Standard electrode potentials are Fe2+/FeE0=0.44; Fe3+/Fe2+E0=0.77 Fe2+,Fe3+ and Fe blocks are kept together. Then 

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a

Fe3+ increases

b

Fe3+ decreases

c

Fe2+/Fe3+remains unchanged

d

Fe2+decreases 

answer is B.

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Detailed Solution

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The metals having higher negative values of their electrode potential can displace metal having lower values from their salt solution

The reactions taking place are ; 

Fe|Fe2+||Fe3+ |Fe2+

Ecello=(+0.44)  +(0.77)= +1.21V

celll reaction is possible. 
Hence, the magnitude of Fe3+ ions will decrease.

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