Q.

Standard electrode potentials are 
Fe2+/Fe,E0=0.44VFe3+/Fe2+,E0=+0.77V
Fe2+,Fe3+ and Fe blocks are kept together, then

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a

Fe2+/Fe3+ remains unchanged

b

  Fe2+ decreases

c

Fe3+ decreases

d

Fe3+ increases

answer is B.

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Detailed Solution

Conversion of Fe2+ to Fe is non-spontaneous while converting Fe3+  to Fe2+ is spontaneous.
So, Fe3+  will be spontaneously converted to Fe2+ . So, Fe3+  will decrease. 

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