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Q.

Standard enthalpy of combustion of benzene, graphite and hydrogen are -3276 kJ mole1-394 kJ mole1 and -286 kJ mole1 respectively.  Standard enthalpy of formation of benzene is ___kJ mole1

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a

+54

b

-76

c

-84

d

+32

answer is A.

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Detailed Solution

C6H6+152O26CO2+3H2O ...(I)

ΔH=-3276

C+O2CO2 ...(II);ΔH=394

H2+12O2H2O ...(III);ΔH=286

6CO2+3H2OC6H6+152O2   ΔH=+32766C            +6O2        6CO2                                 ΔH=394×6=23643H2        +32O2  3H2O¯                                  ΔH=286×3=8586C             + 3H2   C6H6

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