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Q.

Standard enthalpy of formation of N2O5 is -100 kcal/mol and standard entropy of N2,O2 and N2O5 are 35, 40 and 115 kcal respectively, then ΔrG of following reaction at 227° C will be:

2N2+5O22N2O5

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a

1800 kcal

b

+1800 kcal

c

180 kcal

d

80 kcal

answer is B.

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Detailed Solution

ΔSRxn=2×1152×355×40=40

ΔG=ΔHTΔS=200+500×401000=180 kcal

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Standard enthalpy of formation of N2O5 is -100 kcal/mol and standard entropy of N2,O2 and N2O5 are 35, 40 and 115 kcal respectively, then ΔrG∘ of following reaction at 227° C will be:2N2+5O2⟶2N2O5