Q.

Standard enthalpy of vaporisation  for water at 100°C is 40.66 kJ mol–1. The internal energy of vaporisation of water at 100°C (in kJ mol–1) is (Assume water vapour to behave like an ideal gas).

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a

+37.56

b

+43.76

c

+40.66

d

–43.76

answer is A.

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Detailed Solution

H2O(l)H2O(g)vapH = 40.66kJ/mole

ng= 1

H=E+ngRT

E =40.66 - (1×8.314×10-3 ×373) = 37.56 kJ/mole

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