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Q.

Standard entropies of X2,Y2 and XY3 are 60,30 and 50  JK1  mol1 respectively. For the reaction:

 12X2+32Y2XY3,ΔH=30kJ , to be at equilibrium, the temperature should be:

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a

1200 K

b

1000 K

c

750 K

d

500 K

answer is A.

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Detailed Solution

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ΔS for the reaction 12X2+32Y2XY3 is:

ΔS=50(12×60+32×30)=25  J

For equilibrium G=0

ΔG=ΔHTΔS 0=ΔHTΔS T=ΔHΔS   =3000025=1200K.

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